| Foster |
Barnes | Host driver |
| Ethan |
Blake | An aspiring singer |
| Maybelle |
Carter | Country singer (reference) |
| Johnny |
Cash | Country singer (reference) |
| Kenny |
Chesney | Musician-singer |
| Patsy |
Cline | Country singer (reference) |
| Charlie |
Daniels | Singer |
| Officer |
Danvers | One of Anderson's police |
| Jody |
Decker | BMH music agent |
| Susannah |
Dell | One of Graham's talents |
| Clayton |
Dunning | AnnieLee's stepfather |
| Tony |
Graham | Talent manager |
| Merle |
Haggard | Country singer (reference) |
| Kip |
Hart | Famous singer |
| Gus |
Hobbs | AnnieLee's husband |
| Jack |
Holm | Ruthanna's manager |
| Eileen |
Jackson | AnnieLee's publicist |
| George |
Jones | Country singer (reference) |
| Trace |
Jones | Sophia's boyfriend |
| AnnieLee |
Keyes | A singer-songwriter, protagonist. Aka: Pollyanna Poole; Rose McCord; Katie |
| Mary |
Keyes | AnnieLee's mother |
| Jeanine |
Marie | Ethan's ex/boyfriend |
| Tyson |
Mitchell | Photographer |
| Maren |
Morris | Country singer |
| Sarah |
Ortega | Rolling Stone writer |
| Philippe |
Petit | French artist (reference) |
| Aaron |
Price | Talent manager |
| Alice |
Rae | AnnieLee's sister |
| Jimmie |
Rodgers | Country singer (reference) |
| Ruthanna |
Ryder | One of country music's grandest queens |
| Mikey |
Shumer | Promoter |
| Ernest |
Tubb | Country singer |
| Officer |
Tucker | Police officer |
| Kitty |
Wells | Country singer (reference) |
| Hank |
Williams | Country singer (reference) |
| Bob |
Wills | Country musician |
| Anderson |
| Police chief |
| Bella |
| Driver |
| Billy |
| The bartender |
| Blaine |
| Guy at the pawnshop |
| D |
| The man who bought AnnieLee |
| Donna |
| Ethan's bandmate |
| Eddie |
| Truck driver |
| Elrodd |
| One of Ethan's bandmates |
| Gladys |
| Ethan's truck |
| Greg |
| Rhonda's boyfriend |
| Ingrid |
| Bartender |
| Jake |
| AnnieLee's friend who signed with Warner Music |
| Jerry |
| Cain's sound guy |
| Lucas |
| Ruthanna's bodyguard |
| Mary |
| Manager of the event center |
| Maya |
| Ruthanna's assistant |
| Melissa |
| Ethan's bandmate |
| Molly |
| Girl AnnieLee met at the party |
| Poppy |
| Ruthanna's hairstylist |
| Rachel |
| Fashion stylist |
| Ray |
| Pervert old man at the bar |
| Rhonda |
| Motel manager |
| Rick |
| Gus's companion. |
| Samantha |
| Aspiring singer. Aka: Sam |
| Sophia |
| Banjo player, Ruthanna's daughter |
| Stan |
| One of Ethan's bandmates |
| Taylor |
| Girl AnnieLee met at the party |
| Wade |
| Kid from the gas station who found AnnieLee |
